Yes, for best results on sheet metal .023 is essential when using a 220 welder. You can buy a 2Lb spool at Home Depot for $11.47 and 2Lbs is quite a bit of welding.
The thinner wire puts less heat into the material, considering that you can't slow down the wire feed speed as much on a 220 machine as a 110 machine, the thinner wire helps a lot.
Regards,
Joe Dokes