How to do a Basic Wire Splice

I once had some shrink wrap with a "sealer" in it. As it shrunk, this clear gel would squeeze out of it and it would seal water tight. I got it from guy in the electrical lab, but I don't know if it's available to us "common folk". I've tried looking for some ever since, but can't find it at any stores.

Its a little pricy but it is marine or aircraft heat shrink, good stuff. Can be found at boat shops.