Trouble starting

You need to check that the pcm is firing the injectors , use a noid light to check at the injector connector to make sure the pcm drivers are firing the injectors off and on and also makes sure you have power to the injectors.

A video explaining checking injector wiring:
Fuel Injector Noid Light Testing - YouTube

If everything is good there , you may have bad injectors from setting too long.

If your injectors are getting proper signal and able to turn your noid light / injectors off and on. You can remove the fuel rail with injectors, injector wiring and fuel supply line attached and turn the engine over and look for a spray from the injectors to make sure they are working.
Just be sure to remove any chance of spark near the fuel, unplug the coils.

Thanks mate, I bought a little kit which contains a bunch of bulbs and injector fittings. I tested all the fuel injectors and they were all getting signals sent to them. I then moved on to removing the fuel rails and placed a bottle on each injector and cranked it over....NOTHING. I pulled out all of the injectors and wanted to try check if they were in good working order, I found a video on youtube that showed a way on how to test them. All you need is a bit of tubing that can slide over the inlet side of the injector and then the other end over a small syringe. Suck some brake parts cleaner up in to the syringe and then clip a positive and negative on to the injector pins, or use a spare injector harness clip with some stripped wire off the ends if you have one. Then squeeze the fluid and keep pressure on the back of the injector and dab a positive on and off quickly to simulate the pulse they would normally receive. I had 5 of 8 injectors that were blocked and would not come good. A couple came good eventually. I happened to have some SRT8 ones laying around from when I bought the 6.1 fuel rail. I put them in and I heard the sweetest sound known to man! SUCCESS THE HEMI LIVES AGAIN.

Thanks a heap for all your advice and hints along the way guys! I was tearing my hair out but you guy's helped keep me sane and got me through it in the end. I need to order some new 5.7 Injectors as I think it's probably running a bit rich on the 6.1's. I now need to sort my hydraulic clutch out as it won't go in to gear. BUT that's another story. :cheers:

[ame="https://www.youtube.com/watch?v=dTlruNZpMZQ"]Valiant charger with 5.7 Hemi fires to life finally! - YouTube[/ame]