If the head and intake angles are mismatched all across one side or the other, then just shaving the manifold at the existing surface angle won't close that resulting gap at all. The plane of the intake and head surfaces should theoretically be an exact 45.0 degrees from a vertical plane through the engine; if not, they should be matched to at most 0.1 degree tolerance, probably less; every 0.1 degree off of a perfect angle match results in about a .0035" gap opening at top or bottom.