The Edelbrock LD4B is made for the 66 and later head bolt pattern.... The D4B is the one made for the early 64 & 65 heads with the unique 5/16" bolt pattern...
I would recommend using a set of 66 or 67 heads instead to be more compatible with the bolt pattern, or you could enlarge the intake bolt holes in the manifold so the bolts will go in properly... But if you want to keep the intake manifold virgin, then I would go with a set of 273/318 heads from 66 or later... 66 & 67 will have a little smaller combustion chambers to help keep the compression up.... THe edelbrock intakes are getting harder to find and it may be easier to find compatible heads for the LD4B or you will have to modify the intake bolt holes to use the LD4B on the early 65 heads...