One advantage of an ammeter is that is shows charging, how much and when its done. The voltmeter only shows whether the alternator is producing enough power it can potentially charge the battery(s).
If the status of the second battery is important, might be worth having a second ammeter and/or voltmeter for that system. Obviously if you did an ammeter for it, it would be best with an external shunt. The ones for marine and aircraft will probably be the best, and most expensive, as they probably must meet instrumentation certifications for those uses. But those would be a couple of places to search for info and general availability.