Out of curiosity, what DVM are you using?
It may be just fine as is.
I know paint, especially when new, is a hard thing for anyone to scrape off just for a solid ground. Coating on the ECU case can be an issue as well. A ring terminal and separate ground wire under one of the bolts might be an option to consider.
On the volt scale going from ground to ground you'll see nothing. If you go positive batt to negative case is where you'll see any voltage difference compared to across the battery posts.
Not sure on that. In key start any voltage on it?
See post 3 here...……..
Starter won't engage when key is turned.
Does seem to me 12 V to the positive coil (hot wire) should fire in start or run with the key switch unless somethings acting as a kill switch on you?
Do you have a tach or condenser on the coil you could take out of the system while testing?