Overcharging

Welcome to the forum!
Knowing the year and model will be very helpful.
Not all years were wired the same.


That's odd. With no current flowing, voltage should be either system voltage on the positive side or zero on ground side. Electricity can't flow since the wire is not connected.



That indicates there most of the resistance to flow is between the alternator's output stud and the main splice.
Does that make sense to you?

74 Dodge Dart