Blank canvas, steel sided 40x60 pole barn. Thoughts on insulating, electrical, heating???

Hmm. First I heard of prohibitions on using a water heater for floor heat. I bought a Bradford-White 48 gallon propane fired water heater that has factory installed side taps for floor heating service. My system is set up pretty much like yours except I only have it set for 120 degrees.
Here in canada its against building code. At least it was. That was 15 plus years ago.