360 into 1966 valiant

You can also knock the offending corner off the head to get the manifold to sit flat. Mock it up outside the engine compartment and it will be pretty obvious what needs to happen.
Try it if you want, but I wouldn't recommend it. I turned a perfectly good 308 head into scrap iron doing that, and it wasn't because I got carried away with the grinder. There's a water jacket just under the surface there, and it doesn't take much to hit it. I hit it before I even removed enough to get the manifold to sit flat. Some people say they've gotten away with it, but I didn't- and I wouldn't recommend it to anyone else, either.
I may weld it up and keep it as a spare for "someday", but ended up going the header flange route on a new head.