5 digit Zip Codes - Mr Zip! are 1963.
I've seen on line that City codes began in WW2 but with under 100 people, Thompson Falls Montana couldn't have had six postal delivery zones . https://en.wikipedia.org/wiki/Thompson_Falls,_Montana
So I don't know what the Zone 6 is??
In Philadelphia my understanding is the zip codes incorporate the city code at the end. So Philadelphia 1, became 19101.
Then there's US Postal History page that doesn't show any year in the 20th century with 1 cent 1st class postage. ????
So another mystery.
On second/closer look… by the size of print, it was printed by a flat plate. The perf looks like 10 all around. That makes it a Scott#462. First issued 1916.