Exhaust manifold bolts are a but different from water pump bolts. They are smaller 5/16" diameter. Most go through a fairly thine ear on that manifold. Nothing much for it to seize to except the head. Several of the 3/8" water pump bolts go through the timing cover before entering the block so if they are seized they can be seized to that also.
The one close picture we have doesn't really show what this broken bolt goes through but with the approx' 3 threads showing it may be directly into the block and not through a timing cover.