Increasing caster increases camber change in a beneficial manner. As the body rolls in a corner, both wheels lean over, the outside wheel wants to add positive camber and the inside wants to have negative camber. On unequal length A arm suspension you want the outside upper control arm to pull the top of the wheel toward the center of the vehicle. In like manner you want the inside wheel upper control arm to push the top of the wheel out. This works to maintain as much contact patch area on each tire as possible. The outside tire gets the weight transfer and is required to do the most to keep traction in the corner.
Increased caster also aids camber gain in a desireable direction.