La318 cylinder head question

Not snarky.

If a cylinder has a leaking exhaust valve, then;
On the intake stroke, with the carb at idle, that cylinder may find it easier to pull air in from the exhaust manifold, than from the plenum. So it idles rough cuz that cylinder does not have a combustible mixture in it.
If you whack the throttle open, then atmpspheric pressure, being higher than exhaust pressure for at least part of the induction cycle, stuffs some intake charge into the cylinder.
But The Log manifolds are now full of hot expanding gasses and not all of them have finished burning.
If the pressure in the log is higher than the pressure in the cylinder, then the fire can enter the cylinder with the bad valve, set that charge on fire before the intake closes, and Blam, you get a "backfire" in the intake.

If you have witness marks on the piston then yes the head has to come off, and the reason for it to be found and eliminated.
If you find witness marks in other cylinders, my guess is that your spring pressure is inadequate to keep the valve train together, and that the lifters pumped up, trying to do what they're supposed to do.
But if ONLY one valve hit a piston, then there could be other reasons, such as;
a bad lifter
a bad rod bearing,
A jumped timing chain,
A pushrod not sitting in the lifter-cup,
or, yes, a valve stuck open in the guide.
If it was cam timing, with only the exhaust hitting, wouldn’t I still have decent compression on that cylinder? Exhaust would be staying open too long and getting hit, that would mean intake would still be closed on compression, maybe just closing partway through compression stroke? I’m only getting 60psi on that cylinder, if it was closing super late on compression, wouldn’t I be having valves hitting on at least cyl 6 too, if not all of them?

Trying to wrap my brain around the timing on all the cylinders. I’ve got the head off, I’ll turn it by hand tonight and see if it looks like valves are opening way off from when they should be.