Initial timing

lemme add that if its a points distributor then it could be pre-smog, or it could be early CAP/CAS (smog) which had different specs nearly every year.

Download a 1966 Plymouth FSM.
The initial timing for a 225 should be set at slow idle, which should be 550 rpm with the headlights on.
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If you can't get it to idle at 550, at least for the first iternation or two, get it as slow as you can to begin measuring timing vs. rpm.
With a dial back light or a hilly billy timing tape (marks) Measure timing up to at least 2000 rpm. Write it down and plot it. This is enough to see if its an emmissions or pre-emissions set up.