Need some electrical help with my ‘68 Plymouth Valiant 100

Pumping isn't what you need to do.

You need to pump initially, to load as much fluid into the lines as will fit.
Once you get a firm pedal, you need to lean on it, HARD, with all your strength.
If you have power brakes, you need to do it with the engine running, so that the booster is boosting.

With hard, steady pressure, even if there is some air in the lines, you should arrive at a point where everything is as compressed as it can be, and, even if the pedal doesn't get truly hard because of air in the system, the pedal should stay firmly in one position and shouldn't slowly sink down.

If the pedal sinks, you've either got a leak or a bad master cylinder.
Pump it up again, and repeat. After a few cycles, there should be a lot of brake fluid on the ground somewhere. If there isn't, then you have a bad master cylinder.

By the way, how long was this car sitting before you got it?

– Eric
Sorry I realize I didn’t fully respond to this all. It wasn’t being driven as a daily driver as of recently, but the previous owner’s dad would move the car around so it wasn’t just stationary, I’m not sure how much he was actually driving it, though. I know the son (previous owner) used to drive it as his daily driver when he first got it in 2014 and unsure how long he drove it around for.

Also I don’t know if this is helpful, but I’ve noticed around the master cylinder there is splatter spots of what I’m assuming might be brake fluid. Is it possible that could be an indication that the master cylinder is bad?