Is this stuff normal?

Super clean! I love it.
A 5 hour drive is plenty for sure. Did you clean the cap before the extended drive? The white goo should go away with heat but sometimes won't. But if you have the same amount after a long drive, something could be up. I'm with RRR and would pull the valve cover.
Yeah, I kinda realized that after I returned. I should have wiped it away before I left on the five hour drive, then checked it when I got back. I checked inside the valve cover as RRR suggested, and all was well in there. So I'm beginning to think that it's just condensed water that I need to drive out of the motor. BTW, this doesn't happen in the summer, leading me to believe that it isn't a problem with coolant leaking.