the one on the left lets fresh air in
lets say you and your friends just got back from the pool and your hair is all wet, you want to keep it on that setting, because otherwise your windows will fog up like crazy
the one on the right recirculates the air inside the vehicle
if it is really hot out, and you want to quickly turn the temp inside the vehicle down, you run the HVAC at max AC with that vent closed
same goes for really cold days, you run the heater with that vent closed untill the car is comfy
the late 2000s charger had some serious issues with the blend door actuator
when we bought ours in 2009, the actuator had failed and the blend door was stuck closed
it was impossible to drive that car with 2 or more people in it without it fogging up (unless you rolled the windows down)
i "fixed" it by moving the door to the open position and we drove it for 12 years without a problem