I use orange RTV silicone only.
Put and 1/8 inch bead on the neck only and slap it on there wet, wipe off any that squeezed out with a rag while it still uncured.
You will have to put a small bead of it on the surface of the neck where the thermostat seats to hold it there while you put the neck back on.
By the time I fill it with water, it's ready to drive.
I use orange RTV only on my XR500 Honda side covers too (Never leaks a single drop)
You do have to know how to apply it for what you are doing though.
And I HATE seeing it squished out and and not cleaned up, like some people do.
On valve covers I use the rubber gaskets with RTV lightly coating both side of the gasket.
Put it on the car wet, and cinch em down normally.
You will NEVER see a valve cover leak again.
I did this with my roadrunner and just to prove to a friend how well it works, I pulled all the cover bolts out after a day and drove it to his house 7 miles away.
Opened the hood and no valve cover bolts, no leaks either. (Not kidding one bit)